One inch foam is plenty bendy for what you have, so you don't need to sand anything except possibly the bow contour. You need to coat and paint the foam, and a thin veil of glass will add a lot of surface protection. Four ounce deck weave would be plenty to allow you to handle the boat without denting the foam. You should shoot for about 4 inches of draft with a single crew, and adjust the width of the pontoons accordingly. That suggests about 7-8" draft with 2 and gear, so 14" hull depth would be about the minimum practical. As others have mentioned, your hull has a lot of surface area. It isn't the most efficient to propel, so plan on a beefy trolling motor at least. Or a little gas kicker.
You appear to show double bulkheads. They aren't necessary, nor are the wood headers. Just scab the beams to the face of a single bulkhead, glue them, and tab with two layers of 4 once glass extending abut 6 inches down the bulkhead. glue the bulkheads to the hull, fillet the joint, and tab the bulkheads to the hull with 3 inch 9 ounce tape. An old lightbulb makes a good filleting tool for this.
With the small size of the panels the deck has to span, you can easily get away with 6 mm fir or meranti ply. The fir is cheaper, rougher, and will soak up way more epoxy, so I think the meranti will probably work out better in the end. Consider polyester Dynel fabric as it is nonskid if not totally filled epoxy. Or just seal completely with epoxy and apply boat carpet.
Make sure your center of buoyancy and center of gravity match. You want this puppy floating as level as possible, not down by the stern. This doesn't look to be the case at present.