Welcome to the forum Tom.
Re the limited description you mention above of the boat that you would like to build, do you have an existing design in mind which you like, and which you want to use for reference?
If you do, can you post any links please?
Or have you drawn any sketches of what you have in mind? If you have, can you post copies please?
You mention 'pontoons' - do you literally mean typical aluminium pontoons, or do you want your hulls to be more 'boat shaped' (for want of a better description)?
A beam of 11.5' on a length of 38' is not very wide for a catamaran - in fact it is less than what the beam would be on a typical monohull powerboat of the same length. A typical Length / Beam ratio might be about 3 for a 38' monohull, so it would have a beam of maybe 12.5' - a whole foot wider than your cat, and this is a lot really.
Have you done a search on the internet to see if you can find any suitable second hand boats that will do the Great Loop and take you down to the Cays?
Bear in mind that building your own boat will invariably cost a lot more than buying a second hand boat, not to mention the thousands of hours that will be involved in the construction.
And if you engage a naval architect to help you, that will be a significant additional expense as well.
Edit - I did not read the title which mentions the Glen-L 32' boat - are you referring to the 'Super Huck' 32' pontoons mentioned in the link below?
Super Huck https://www.glen-l.com/super-huck/
Be aware that if you add an extra pontoon to an already narrow catamaran to create a trimaran, then this will increase the resistance enormously (especially so with wave interference effects between the hulls) - not to mention reduce the sea keeping ability.
And you will need reasonable seakeeping ability if you want to take this boat to the Cays (I presume you mean the Florida Cays?)
Edit again - you later mentioned the Mark Twain series (either 36' or 40') - do you still want to convert this into a trimaran (tritoon?) as well?
Mark Twain Series https://www.glen-l.com/mark-twain-series/