As Lewisboats said, the vinyl from Walmart works well. It is soft enough to let you roll out the bubbles, but is still stiff enough to give a good finish. It can still be a bit "wavy" just due to the nature of the vinyl, it is not as stiff as the Mylar. The Mylar produces a flatter surface.
Trying to use it on a smooth surface is going to be tough. I used it over wood with 6 oz glass and the vinyl worked well. I was able to roll out all the bubbles and the result was excellent, although there was just a touch of "waviness" in it. The .030" thick Mylar produces a flatter surface, but it is considerably harder to get all the bubbles out of the surface. If you don't get virtually all the bubbles out it isn't worth doing. That's just my opinion, but it's based on experience with the process. If you are doing a flat surface, like a table top or a flat deck it is easier if you have something of a rough surface, like using the mylar to give you a flat surface for filling the weave.
I tried to use the .030" mylar on a surface that had some brush strokes in it, but was pretty smooth, and that was a disaster, I ended up peeling it off when I couldn't get the bubbles out because the amount of epoxy was too thin.
Also, this process works better with thicker viscosity epoxy than the thinner stuff, particularly when you are doing it in a thinner layer. The really thin stuff doesn't work as well unless there is cloth in there at the same time. Again, just my experience.