View Full Version : Synthetic lubricants vs petroleum lubricants for diesels


Greenseas2
05-02-2006, 07:34 AM
Within the past two years, automobiles coming from dealerships have had synthetic oils in them that are recommended to be changes every 10,000 miles rather than the 3,000 miles for petroleum based oils. This year we drained the petroleum oils from a Yanmar diesel and flushed the system with synthetic oils then filled the engine with Mobile 1. The engine appears to run better and has no smoke during cool weather start up. Even though synthetic oils cost more, they are advertised to extend engine life by almost double. Additionally, this is another step away from big petroleum producers and OPEC as synthetics are formulated and made by chemical companies, but stocked by oil company gas stations. The products are available directly from chemical firms in bulk.

solrac
05-02-2006, 05:44 PM
mmmm... would recommend you reading the small leters on the back of the bottle, the "Synthetc" oils peroleum companies are distributing all around the world, are not 100% synthetic, mostly they are "blendings" made of 20% to 40% synth and the rest is base petroleum oil... (sorry...) the improved part of the tale is the synth part is no more than the old good "aditive" (injector cleaner + anti smoke and some others) another big lie of the Petroleum Companies...
the better the quality, the higher the classification it states in the bottle (API SG, SH...)
Lube oil has a couple major issues:
- Viscosity Loss (as engine produces heat, the carbon chains begin breaking, there is nothing you can do against but changing oil)
- humidity (diesel engines compress air & injects fuel, in that compression, vapour is generated inside combustion chambers & some of it trespass the o-rings mixing with oil)
- carbon (similar thing, carbon is produced during ignition & shoved by o-rings to the oil)
Is a common practice on Petroleum Companies to provide oil analysis to customers, you just may ask for this service (it's free of charge). They will give you the results of any sample you provide.
May I recommend the better option can be using a multigrade base oil (SH class) + some anti smoke + some injector cleaner. the final result would be near the same with a fraction of the cost.

Greenseas2
05-02-2006, 08:23 PM
Thanks I'll try the other oils and see what happens and the lower price is a plus.

solrac
05-02-2006, 08:36 PM
you can see the size of the lie on some company lubes datasheets:

http://www.shell.com/home/Framework?siteId=uy-es&FC2=/uy-es/html/iwgen/hojas_de_seguridad/zzz_lhn.html&FC3=/uy-es/html/iwgen/hojas_de_seguridad/lubricantes_010904.html

http://www.mobiloil.com/USA-English/MotorOil/Oils/Oils.aspx

do you figure why are they offering separate additives for oil? why do you need to add an aditive to an oil that has it?:D :D

SAQuestor
05-02-2006, 10:28 PM
is located at: 34'54"35"47S - 56'07"48"98W

So which boat is yours? :p

gonzo
05-04-2006, 09:18 AM
Syntetic oils last much longer. They are petroleum oils modified to make the molecules longer. Oil molecules break down with use, get shorter and loose viscosity. If you start with a longer molecule it lasts longer. The additives are anti-foaming, detergents, viscosity modifiers and anti-acids. No lies there.

StianM
05-04-2006, 11:54 AM
Syntetic oil's come form crude oil just like anny other oil.

When Light fractions like gas, gasoline, diesel and parafine there will be some leftovers at the bottom off the destilation tower.
This can not be destilated because it would require so mutch heat that it would harme the product.
It's there for pumped into a new tower that is operating under vacume so it neads les heat to avaporate. This vacume destilate is what is the base for lubrication oil.
By manipulating the molecules you change the oil's capabiletys and all oil manufactors know how the perfect oil look like and everyone is trying to get as close to it as posible.
Manipulating like this is exspensive so it's normal that they sometime mix it with unmanipulated oil to save cost.
If someone say they are not made from petrolium, they are wrong.

solrac
05-04-2006, 06:56 PM
So which boat is yours? :p

Answer on the photo...

solrac
05-04-2006, 07:06 PM
Syntetic oil's come form crude oil just like anny other oil.

When Light fractions like gas, gasoline, diesel and parafine there will be some leftovers at the bottom off the destilation tower.
This can not be destilated because it would require so mutch heat that it would harme the product.
It's there for pumped into a new tower that is operating under vacume so it neads les heat to avaporate. This vacume destilate is what is the base for lubrication oil.
By manipulating the molecules you change the oil's capabiletys and all oil manufactors know how the perfect oil look like and everyone is trying to get as close to it as posible.
Manipulating like this is exspensive so it's normal that they sometime mix it with unmanipulated oil to save cost.
If someone say they are not made from petrolium, they are wrong.

would you excuse me for correcting you:
what you are figuring is a "cathalytic cracking tower" mostly used as you said, to "crack" longer chained molecules into shorter ones, ok, the only thing you forgot is, shorter chains equals lighter products (ie, you feed the tower with asphalts and get from gasolines,up to gas), never oils. Oil is out on the bottom third part of the first tower... (sorry:) )
maybe your confusion is on the "multigrade oils", they are blended from different lenght chains (not so different at all), the advantage is as you said, different lenght chains do "break" at different heating points, so, in a medium term, as the first broken are the longest, still "survive unbreakened" the shorter ones, improving viscosity.
Alas, the major need for oil change is rarely viscosity loss (at least in multigrade, classification SH oils), is mainly carbon, as it's isolated molecules some orders of magnitude smaller than oil chains, they live in the "spaces" inter oil-molecules without increasing the whole volume (what a rough descriptoin, sorry again:D )
Once I've heared that during World War 2, the Germans implemented some kind of "filtering mobile plant" they used to sepparate carbon from oil on tanks and trucks to re-use the same oil (not confirmed)
you can do a home experiment, use a couple metal can's & a coffe paper filter, heat an oil sample (not more than 60ºc & in a ventilated room or outside), slowly pour the heated liquid through the paper filter to the other can, let it go to ambient temp a couple hours, & see the result...

StianM
05-04-2006, 10:05 PM
would you excuse me for correcting you:
what you are figuring is a "cathalytic cracking tower"

Cathalytic cracking is something else. Here you add a catalysator to the crude oil too evaporate out heavy oil fractions. (aluminium oxsyde I belive)

mostly used as you said, to "crack" longer chained molecules into shorter ones, ok, the only thing you forgot is, shorter chains equals lighter products (ie, you feed the tower with asphalts and get from gasolines,up to gas), never oils. Oil is out on the bottom third part of the first tower... (sorry:) )

Both gasoline and diesel are oil's



Alas, the major need for oil change is rarely viscosity loss (at least in multigrade, classification SH oils), is mainly carbon

With all respect, Oil's are Hydro Carbones. If you have no Carbon it's all a hydrogen gas.


Once I've heared that during World War 2, the Germans implemented some kind of "filtering mobile plant" they used to sepparate carbon from oil on tanks and trucks to re-use the same oil (not confirmed)


Remove the carbon and you will only have the hydrogen left. Hydrogen gas is not a good lubricant. There are how ever devices to separate carbon particles from combustion and metal particles from the oil. In this case your engines lube oil consuption will be high enought that it's almoust enough only refilling the oil and not change it.

This is done by sentrifuges withc produce up to 9000g.
You can buy one from www.alfa-laval.com or www.gea-westfalia.com

longliner45
05-04-2006, 10:17 PM
here in GM town ,,,,,,,Dayton Ohio. all the guys at gm are using synthetic , they say the only problem is it is so good that it cleans the engine out and they have leaks ,,,only on old engines, they say that they get are getting an extra 100000 miles and better fuel economy and better engine wear.

StianM
05-05-2006, 04:33 AM
here in GM town ,,,,,,,Dayton Ohio. all the guys at gm are using synthetic , they say the only problem is it is so good that it cleans the engine out and they have leaks ,,,only on old engines, they say that they get are getting an extra 100000 miles and better fuel economy and better engine wear.

I hear those storry too. Dirt sealing cracks in gaskets are washed away and you get leak's, but for sealing betwen the liner and pistion it's supreeme.

FAST FRED
05-05-2006, 06:32 AM
There is little problem with using Syn oil in a daily used work boat.

The hassle is most pleasure boats seldom get used , so the DOWNSIDE of Syn oil becomes a headache.

The Syn oils do NOT give anywhere near the rust prevention that old perto oils do , so should be removed for layup.

Thjs gets really tiedious , although some folks will save the preserving oil and re install it for a few winter storage sints.

Engines designed to use Syn oil will have closer tolerances and different seals and sealing goop unsed on assembly.

I would use a Syn oil in a manual transmission (like a Twin Disc) where there is less hassles with rust and corrosion, but not in my antique 6-71 as it would leak like a sive , and enjoy NO benifits from the pricy oil.

"but for sealing betwen the liner and pistion it's supreeme."

Sorry the rings do the sealing ,
the Syn oil gets scraped off at lower power cost , which is where the "better" economy comes from.


FAST FRED

StianM
05-05-2006, 07:05 AM
"but for sealing betwen the liner and pistion it's supreeme."

Sorry the rings do the sealing ,
the Syn oil gets scraped off at lower power cost , which is where the "better" economy comes from.


FAST FRED

Wrong. If you don't get a oil film on the liners surface your engine would drink oil like a sailor drink rom. If the oil got scraped off you would also have suffing. Only some off the oil is scraped off. betwen the piston ring and the cylinder liner there is something called a hydrodynamical lubrication.

What is the oil's job's?
1.lubricating.
2.cooling.
3.cleaning.
4.sealing.
You all learnet this at a point right?

gonzo
05-05-2006, 07:58 AM
Syntetic oils like Amsoil marine have superior corrosion protection. Fast Fred: syntetic oil is a modified hydrocarbon. Where did you hear it has to be removed for layup? Also, engines are not designed differently for syntetic oil. Any engine can use it as long as it is broken in. Because syntetic oil is so highly lubricant, hard piston rings won't seat properly with it.

SheetWise
05-05-2006, 03:26 PM
Does anyone have experience with oil polishing (http://www.pcxhost.com/store/st7/tp8/home.jsp?unique=1146857378968&sid=2029205585FFFD4A4012523E3C9295085342FB7E&SessionID=4969439&source=launch) systems?

SheetWise
05-05-2006, 03:29 PM
From the previously linked site --

"On June 21st, 1999 at 1,012,825 miles, this Peterbilt rolled into Covington Detroit Diesel for its third internal inspection in nine years. The report card for the first two inspections read Exceptionally clean engine and NO measurable wear. Finally, at 1 million miles, the only measurable wear that could be found was on the rings. That same truck is back on the road with the original bearings, liners, cam and the OLD conventional petroleum oil, which has now run 1 million miles since the last oil change.

How did this happen? The owner simply changed the inexpensive Gulf Coast Filter elements every 10,000 miles and the factory full flow filters every 30,000 miles. By following this safe and simple maintenance schedule, the oil stayed clean 100% of the time and wear was drastically reduced within the engine."

Link (http://www.pcxhost.com/store/st7/tp8/support/custom.jsp?id=1341&unique=1146857512968&sid=2029205585FFFD4A4012523E3C9295085342FB7E).

FAST FRED
05-06-2006, 06:25 AM
The Detroit series 60 REGULARLY go that 1,000,000, in a few years of truck use, at 150,000- 200,000 miles a year.

Since
little down time equals no rusting of the cylinders , it is not suprising the engine would continue , with or without a roll of toilet paper or paper towels as an added "Majic " filter.

Syntetic oils like Amsoil marine have superior corrosion protection.

HMMM, the filter people Raycore are touting/selling Rust Inhibitors for synthetic lube to help "solve" the rusting hassles.

Are they screwing stoopid folks?

Or attempting to solve an ongoing problem?

FAST FRED

StianM
05-06-2006, 06:49 AM
From the previously linked site --

"On June 21st, 1999 at 1,012,825 miles, this Peterbilt rolled into Covington Detroit Diesel for its third internal inspection in nine years. The report card for the first two inspections read Exceptionally clean engine and NO measurable wear. Finally, at 1 million miles, the only measurable wear that could be found was on the rings. That same truck is back on the road with the original bearings, liners, cam and the OLD conventional petroleum oil, which has now run 1 million miles since the last oil change.

How did this happen? The owner simply changed the inexpensive Gulf Coast Filter elements every 10,000 miles and the factory full flow filters every 30,000 miles. By following this safe and simple maintenance schedule, the oil stayed clean 100% of the time and wear was drastically reduced within the engine."

Link (http://www.pcxhost.com/store/st7/tp8/support/custom.jsp?id=1341&unique=1146857512968&sid=2029205585FFFD4A4012523E3C9295085342FB7E).

As long as you can mantain a hydrodynamical lubrication it wont be anny wear simply because the part's are not in contact with eatch other. Some large diesels have primerpumps that are started befour the engine is turned. This make shure that all oilpipes and chanels inside the engine has preshurised oil at start up.

FAST FRED
05-07-2006, 05:58 AM
"Some large diesels have primerpumps that are started befour the engine is turned. This make shure that all oilpipes and chanels inside the engine has preshurised oil at start up."

LARGE is the keyword here , a simple Series 60 has no pre oiler.

Pre- oiling can "save" the engines bearings and cam from wear at startup , and is frequently done on LARGE (2000hp and UP) engines.Where the lube oil is pre heated too.

For a seldom used boat the expense of a pre oil pump and hardware is not required.

If the owner will fit a 2 or 3 gallon accumulator with an electric valve the pre oil is seamless.

The switched valve is opened letting the oil in the accumulator pressurize the engines lube oil circuit.

The engine is started and after 2 min of operation the the valve switch is closed.

The oil will lubricate the engine & then is returned to the accumulator during that first 2 min when the oil pressure is highest.

NONE of this solves the problems of internal rusting with synthetic oil.

FAST FRED

StianM
05-07-2006, 10:04 AM
I never see a engine have rust inside off it because it use syntetic oil.
If that hapens I woul recomend to change oil suplier.

ted655
06-29-2006, 05:15 PM
From what I've been told, Syns have one drawback. Drainoff. They don't cling to surfaces as long. Startups are drier. A pre-pressured (or prestart) oil system is the cure.
Some advocate "mixing" regular oil (20%) to solve the problem.

Ari
06-29-2006, 11:52 PM
From what I've been told, Syns have one drawback. Drainoff. They don't cling to surfaces as long. Startups are drier. A pre-pressured (or prestart) oil system is the cure.
Some advocate "mixing" regular oil (20%) to solve the problem.
Mixing normal luboil with synthetic luboil is bad..the reason is type of additive used in both oil is different. The different chemical might not be compatible.This normally will result in the mixed oil became coagulate..turn to jelly.This process might take some time to complete..it is the same with other type of after market additive. If those product are compatible then it is O.K..if it is not..disaster..! Fully synthetic product are develop for the more advance or newer engine that have tighter clearance with variable temperature e.g: engine with turbo.turbo bearings needs luboil that can remain intack even when it is very thin and not turn to coke in the process, rockers doesn't need that high a quality and ability and the temperature is lower than what face by a turbo bearings..Synthetic luboil can perform this task real good. Engine that have very high RPM like 5000 and above will be very benificial with synthetic engine oil.It is the carbon particle/coke and some metal from engine erosion that mainly contribute to the inability to lubricate properly. Oil have the tendency to degenerate..that mean they have life span, so oil that been used a few hours in the engine and left for maybe six month without used won't be as good as before the 6 months lay off.:)

View Full Version : Synthetic lubricants vs petroleum lubricants for diesels